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Description Representation of an isocyanide as a linear carbene stabilized through delocalization of the nitrogen lone pair.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal -
Description X‐ray structure of the thioimidate 4 b, DIAMOND representation, thermal ellipsoids are drawn at 50 % probability level.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal -
Description Reaction of magnesiated aldimines 3 with various electrophiles followed by acidic cleavage.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal -
Description Condition screening for the reaction of 2,4,6‐trichlorophenyl isocyanide 1 with the phenylmagnesium halide 2 a.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal -
Description Reaction of the isocyanide 1 with Grignard reagents followed by trapping of the formed magnesiated aldimines 3 with various electrophiles.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal -
Description Reaction of magnesiated aldimines 3 with various Weinreb amides followed by acidic cleavage leading to 1,2‐diketones 6.
Article Title: Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6‐Trichlorophenyl Isocyanide: Synthesis of 1,2‐Dicarbonyl Derivatives
Publication Title: Chemistry – A European Journal