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Description 1H NMR spectra (CDCl3): i) MVL, ii) P(MVL)ROP, and iii) P(MVL)VAP monomer for comparison.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description Post‐functionalization of P(MVL)ROP via Photocuring and the Thiol–Ene click reaction.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description 1H NMR spectra (CDCl3): a) MVL monomer for comparison; b) P(MVL)ROP; c) the liquid product obtained after heating neat P(MVL)ROP with Sn(Oct)2 at 150 °C for 1 h; and d) P(MVL)ROP obtained after...
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description Overlay of the 1H NMR (CDCl3) spectra of i) P(MVL) and ii) P(MVL)ROP‐SR for comparison.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description Previously reported uncontrolled VAP of MVL versus the ROP and controlled VAP of MVL reported herein, leading to either recyclable or post‐functionalizable unsaturated polyester P(MVL)ROP and...
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description Results obtained from the MVL polymerization by NHC/ROH catalyst/initiator systems
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description MALDI‐TOF mass spectrum of the low‐MW P(MVL)ROP produced by IiPr in toluene at 25 °C (Run 10, Table ). Inset: plot of m/z values (y) versus the number of MVL repeat units (x).
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description 1H NMR spectra (CDCl3) of PhCH2O–[(MVL)ROP]n–H by IiPr/PhCH2OH.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description 1H NMR spectra (C6D6) of a) BnOH, b) [BnOH]/[MVL] = 5/1, c) [BnOH]/[MVL]/[DMF] = 5/1/40, and d) [BnOH]/[DMF] = 1/4.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description Proposed Mechanism for the A) NHC‐Catalyzed ROP and B) VAP of MVL.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description 1H NMR spectra (C6D6) of a) BnOH, b) [BnOH]/[IiPr] = 1/1, c) [BnOH]/[IiPr]/[DMF] = 1/1/40, and d) [BnOH]/[DMF] = 1/4.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics -
Description N‐heterocyclic carbene catalysts used for the polymerization of MVL.
Article Title: Recyclable Vinyl‐Functionalized Polyesters via Chemoselective Organopolymerization of Bifunctional α‐Methylene‐δ‐Valerolactone
Publication Title: Macromolecular Chemistry and Physics