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Description A) In situ proteome profile of IA‐labeled MCF‐7 cells pre‐treated with different concentrations of DNS‐pE (0 to 50 μm, 3 h). Upon IA probe labeling (1 μm), cells were clicked reaction with Rh‐N3...
Article Title: A Vinyl Sulfone‐Based Fluorogenic Probe Capable of Selective Labeling of PHGDH in Live Mammalian Cells
Publication Title: Angewandte Chemie International Edition -
Description Variations of SRO2 (circles) and SHOOQO2 (triangles) as function of RH. Green: 1‐butyl‐O2; blue: 1‐pentyl‐O2; red: 1‐hexyl‐O2; black: 2,5‐dimethylhexyl‐O2. Dotted and dashed lines are linear...
Article Title: Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: An Experimental and Theoretical Study
Publication Title: Angewandte Chemie International Edition -
Description Formation of drug‐core thin‐silica‐shell nanocomposites with high drug loading. A) Demonstration showing the formation of drug‐core thin‐silica‐shell nanocomposites using the tri‐modular peptide...
Article Title: Bioinspired Core–Shell Nanoparticles for Hydrophobic Drug Delivery
Publication Title: Angewandte Chemie International Edition -
Description a) The fs‐TA spectra (pump at 400 nm) taken at several representative probe delays for UiO‐66‐NH2‐0 and UiO‐66‐NH2‐100. b) fs‐TA kinetics and the global fitting results (probing in the range...
Article Title: Switching on the Photocatalysis of Metal–Organic Frameworks by Engineering Structural Defects
Publication Title: Angewandte Chemie International Edition -
Description Gram‐scale reaction and mechanistic investigations.
Article Title: Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis
Publication Title: Angewandte Chemie International Edition -
Description The scope of Pd‐catalyzed [4+3] allenylic cycloaddition/cross‐coupling. See the Supporting Information for detailed reaction conditions.
Article Title: Regioselectivity Switch in Palladium‐Catalyzed Allenylic Cycloadditions of Allenic Esters: [4+1] or [4+3] Cycloaddition/Cross‐Coupling
Publication Title: Angewandte Chemie International Edition -
Description a) The high stability of indigo has its mechanism associated with a fast ESPT: the keto excited species is converted into its enol isomer. b) (top) Photographic detail of an Andean textile (Man's...
Article Title: Photochemistry of Artists’ Dyes and Pigments: Towards Better Understanding and Prevention of Colour Change in Works of Art
Publication Title: Angewandte Chemie International Edition -
Description Survey of N‐triflylphosphoramide catalysts for the enantioselective Brønsted acid catalyzed carbonyl‐ene reaction.[a]
Article Title: Highly Enantioselective Organocatalytic Carbonyl‐Ene Reaction with Strongly Acidic, Chiral Brønsted Acids as Efficient Catalysts
Publication Title: Angewandte Chemie International Edition -
Description a) UV/Vis absorption and fluorescence (FL) spectra of 6 in DCM (c=1×10−5 M; λex for FL: 330 nm); b) calculated frontier molecular orbital profiles, energy diagram, and major electronic transitions...
Article Title: Synthesis of a Sidewall Fragment of a (12,0) Carbon Nanotube
Publication Title: Angewandte Chemie International Edition -
Description Structure characterization of VS2, 2D amorphous VS2, and 2D VO2(D). a) XRD patterns, b) XPS survey, and high‐resolution XPS spectra of c) V 2p and d) S 2p.
Article Title: Accurate Control of VS2 Nanosheets for Coexisting High Photoluminescence and Photothermal Conversion Efficiency
Publication Title: Angewandte Chemie International Edition -
Description a) Top and side views of the most stable configuration found for the Au(111)‐39×39 R16.1°‐2BTAI system. C, N, Au and H atoms shown as brown, gray, pale green and small white spheres, respectively....
Article Title: Synthesis and Two‐Dimensional Chiral Surface Self‐Assembly of a π‐Conjugated System with Three‐Fold Symmetry: Benzotri(7‐Azaindole)
Publication Title: Angewandte Chemie International Edition -
Description Schematic illustration of the principle of controlling molecular cleavage and degradation. a) Traditional design for triggered molecular cleavage in the presence of one specific stimulus (S). b) A...
Article Title: Programmed Degradation of Hydrogels with a Double‐Locked Domain
Publication Title: Angewandte Chemie International Edition -
Description A) SDS‐PAGE of sfGFP‐1am expressed with or without (NA) an ncAA (n.d.=not detected). B) LC‐MS of A (predicted: sfGFP‐1IF 27 898 Da; sfGFP‐1AzF 27 813 Da; sfGFP‐1MeF 27 786 Da; sfGFP‐1NapA 27 822...
Article Title: Initiation of Protein Synthesis with Non‐Canonical Amino Acids In Vivo
Publication Title: Angewandte Chemie International Edition -
Description Hydrodynamic radii (Rh) of hLys and mutants obtained from translational diffusion measurements34 (600 MHz in D2O at pH 2, 293 K).
Article Title: Characteristics of Human Lysozyme and Its Disease‐Related Mutants in their Unfolded States
Publication Title: Angewandte Chemie International Edition -
Description Versatility of the primary and tertiary boronic esters 4 a and 5 a [DG=(Me2C=N‐O)].Reaction Conditions: a) CsF or KF, MeCN/H2O; b) BCl3, DCM; c) BCl3, DCM; MIDA, DMSO; d) LiCH2Cl, −78 °C Et2O; e)...
Article Title: Ligand‐Controlled Regiodivergent Enantioselective Rhodium‐Catalyzed Alkene Hydroboration
Publication Title: Angewandte Chemie International Edition -
Description Cycloaddition reactions between aluminyl anions 6, 7 and 11 and various unsaturated substrates.
Article Title: The Aluminyl Anion: A New Generation of Aluminium Nucleophile
Publication Title: Angewandte Chemie International Edition -
Description Relative free energies of the possible diastereomers of 8.13
Article Title: Aldehyde Umpolung by N‐Heterocyclic Carbenes: NMR Characterization of the Breslow Intermediate in its Keto Form, and a Spiro‐Dioxolane as the Resting State of the Catalytic System
Publication Title: Angewandte Chemie International Edition -
Description Table
Article Title: Multispecific Platinum(IV) Complex Deters Breast Cancer via Interposing Inflammation and Immunosuppression as an Inhibitor of COX‐2 and PD‐L1
Publication Title: Angewandte Chemie International Edition -
Description Table
Article Title: Supramolecular Catalysis of the oxa‐Pictet–Spengler Reaction with an Endohedrally Functionalized Self‐Assembled Cage Complex
Publication Title: Angewandte Chemie International Edition -
Description a) Confocal images of HeLa cells containing FAM‐17S‐IBQ along with 17Dz‐FQ, BO‐17Dz‐FQ or PS‐17Dz under different conditions as indicated. b) Flow cytometry analysis of the cell samples with...
Article Title: Orthogonal Activation of RNA‐Cleaving DNAzymes in Live Cells by Reactive Oxygen Species
Publication Title: Angewandte Chemie International Edition -
Description Preliminary evaluation of reaction conditions for in situ generation of HPD‐mediating iodanes from iodoarenes.[a]
Article Title: Asymmetric Hydroxylative Phenol Dearomatization through In Situ Generation of Iodanes from Chiral Iodoarenes and m‐CPBA
Publication Title: Angewandte Chemie International Edition -
Description a) Diagram of the chemical structure and synthesis of Ni‐BTA. b) Diagram of planar 1D conjugated coordination polymers Ni‐BTA (side and top view, respectively). c) Herringbone packing motif of...
Article Title: A One‐Dimensional π–d Conjugated Coordination Polymer for Sodium Storage with Catalytic Activity in Negishi Coupling
Publication Title: Angewandte Chemie International Edition -
Description Site‐selective cross‐coupling.[a]
Article Title: Copper‐Catalyzed Cross‐Coupling Reaction of Organoboron Compounds with Primary Alkyl Halides and Pseudohalides
Publication Title: Angewandte Chemie International Edition -
Description The H2 adsorption capacities at 77 K for PdNPs@[SNU‐3]x+(NO3−)x with various amounts of loaded PdNPs.
Article Title: Enhanced Hydrogen Storage by Palladium Nanoparticles Fabricated in a Redox‐Active Metal–Organic Framework
Publication Title: Angewandte Chemie International Edition -
Description In vivo innate immune activation by lipid–polymer amphiphile conjugates. A) TLR agonistic activity measured as NF‐kB activation by a RAW‐Blue reporter assay. (n=6, mean + SD). B) FACS analysis of...
Article Title: Potent Lymphatic Translocation and Spatial Control Over Innate Immune Activation by Polymer–Lipid Amphiphile Conjugates of Small‐Molecule TLR7/8 Agonists
Publication Title: Angewandte Chemie International Edition -
Description C‐glycosylations of galactose donor 1 b and lactose donor 1 c.
Article Title: Versatile Glycosyl Sulfonates in β‐Selective C‐Glycosylation
Publication Title: Angewandte Chemie International Edition -
Description Mechanistic studies.
Article Title: Modular Access to Eight‐Membered N‐Heterocycles by Directed Carbonylative C−C Bond Activation of Aminocyclopropanes
Publication Title: Angewandte Chemie International Edition -
Description Current‐time recording of the Azo‐modified membrane with UV/β‐CD, Vis/β‐CD and UV/Vis/β‐CD. The voltage is −1 V.
Article Title: Bacteriorhodopsin‐Inspired Light‐Driven Artificial Molecule Motors for Transmembrane Mass Transportation
Publication Title: Angewandte Chemie International Edition -
Description A) Simplified qualitative molecular orbital interaction diagram between the LUMO (a) of the [Pd4(CNT)(COT)]+ fragment (only dz2 orbitals are shown for clarity) and the out‐of‐phase combination (b)...
Article Title: Exceeding Metal Capacity in Sandwich Complexes: Ligand‐Unsupported Docking of Extra Metal Moieties at Edges of a Metal Sheet Sandwich Complex
Publication Title: Angewandte Chemie International Edition -
Description A) Schematic illustration of A&MMP@Ag2S‐AF7P for NB detection. B) TEM image of A&MMP@Ag2S‐AF7P. C) The hydrodynamic diameters of various nanoparticles. D) Absorbance and fluorescence spectra of...
Article Title: Rapid Unperturbed‐Tissue Analysis for Intraoperative Cancer Diagnosis Using an Enzyme‐Activated NIR‐II Nanoprobe
Publication Title: Angewandte Chemie International Edition